|
二维码(扫一下试试看!) |
铁改性膨润土光催化剂的制备、表征及应用 |
Preparation, Characterization and Application of Fe-Bentonite Photocatalyst |
|
DOI:10.11980/j.issn.0254-508X.2015.11.005 |
关键词: 铁改性膨润土 光催化 非均相Fenton 造纸法烟草薄片废水 |
Key Words:Fe-Bentonite heterogeneous Fenton tobacco slice wastewater |
基金项目:国家水体污染控制与治理科技重大专项(2014ZX-07213001)。 |
作者 | 单位 | 莫立焕 | 华南理工大学制浆造纸工程国家重点实验室,广东广州,510640 | 谈金强 | 华南理工大学制浆造纸工程国家重点实验室,广东广州,510640 | 王聪聪 | 华南理工大学制浆造纸工程国家重点实验室,广东广州,510640 | 徐 峻 | 华南理工大学制浆造纸工程国家重点实验室,广东广州,510640 | 周志明 | 华南理工大学制浆造纸工程国家重点实验室,广东广州,510640 | 何帅明 | 华南理工大学制浆造纸工程国家重点实验室,广东广州,510640 | 李 军 | 华南理工大学制浆造纸工程国家重点实验室,广东广州,510640 |
|
摘要点击次数: 6022 |
全文下载次数: 1803 |
摘要:以膨润土作为载体,制备了铁改性膨润土光催化剂,采用多种手段对其结构进行表征,将制备的铁改性膨润土光催化剂用于非均相Fenton法深度处理造纸法烟草薄片废水,考察了铁改性膨润土光催化剂的催化活性及稳定性。结果表明,膨润土经铁改性后X射线衍射(XRD)峰强度略有减弱,基本骨架未产生太大变化,层状结构变得疏松,比表面积也增大,膨润土经铁改性后Fe2O3的含量增加。对于CODCr值为365 mg/L的造纸法烟草薄片废水,当反应初始pH值为3.0、H2O2用量为3.0 mL/L、铁改性膨润土光催化剂用量为1700 mg/L时,采用光催化非均相Fenton法处理3 h时,废水CODCr的去除率达到80.2%。另外,铁改性膨润土催化剂具有较高的稳定性和较好的可重复使用性,催化剂的重复使用并不会改变原来的骨架及微观形貌。 |
Abstract:The structure characterization of Fe-Bentonite which was prepared through cation exchange was studied by X-ray diffraction(XRD), fourier transform infrared spectrometer(FT-IR), scanning electron microscopy(SEM), N2 adsorption-desorption, laser particle size analyzer and X-ray fluorescence (XRF).The results showed that the intensity of its characteristic apex fell a little bit, its the basic skeletons didnt change much,the layered structure became loose, the specific surface area and the Fe2O3 content increased. CODCr removal rate of the effluent with CODCr content of 365 mg/L and initial pH value was 3.0 could reach 80.2% when the dorages of H2O2 and Fe-Bentonite were 3.0 mL/L and 1700 mg/L respectively, under the UV irradiation for 180 min, the Fe ions amount in solution leaching from the Fe-Bentonite was relatively low, and the catalyst could be easily recovered and reused, repeated use would not alter the skeleton and morphology of Fe-Bentonite. |
查看全文 查看/发表评论 下载PDF阅读器 |
|
|
|