戊二醛接枝季铵型阳离子PVA与PAE协同作用对纸张的增强

Combined Application of Cationic Polyvinyl Alcohol Modified by Glutaraldehyde and PAE in Paper Manufacture

关键词:  阳离子聚乙烯醇  戊二醛  PAE  湿强性能

Key Words:cationic polyvinyl alcohol  glutaraldehyde  PAE  wet strength

摘要:以3-氯-2-羟丙基三甲基氯化铵对聚乙烯醇(PVA)进行阳离子化改性制得阳离子聚乙烯醇(QPVA),并加入戊二醛进行交联反应,制备戊二醛接枝季铵型阳离子聚乙烯醇(GQPVA)。采用红外光谱对其结构进行了表征；用元素分析仪测定QPVA氮含量,得出醚化度；并以GQPVA为增强剂,少量聚酰胺多胺环氧氯丙烷（PAE）为交联剂,添加到浆中用以提高纸张湿强性能,探讨了GQPVA-PAE用量对纸张性能的影响。结果表明,当GQPVA-PAE树脂用量为1%(对绝干浆)时,与单独使用PAE相比，湿抗张指数提高了11.8%,抗张强度保留率提高了6.88%,抗张指数提高了6.94%,撕裂指数提高了8.27%,纸张耐折度提高了26.2%。

Abstract:A novel cationic polyvinyl alcohol (GQPVA) was prepared by modification of polyvinyl alcohol with 3-chloro-2-hydroxypropyltrimethyl ammonium chloride and with glutaraldehyde as cross-linker. The corresponding structure was characterized by IR. The Nitrogen element content of cationic polyvinyl alcohol was investigated by element analyzer. GQPVA-PAE composite wet strength agent was used in papermaking process to increase the crosslinking among fibers. And the effect of GQPVA dosage on the strength of paper was studied. The result indicated that when the dosag of GQPVA-PAE was 1% (on od fiber mass) the wet and dry tensile index increased by 11.8% and 6.94%, respectively, tensile index retention rate increased by 6.88%. Tearing index and folding endurance increased by 8.27% and 26.2%, respectively.