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纳米MnOx负载纸的制备及其甲醛去除性能的研究 |
Preparation of Nano MnOx-loaded Paper via in Situ Synthesis and Its Performance for Formaldehyde Removal |
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DOI:10.11980/j.issn.0254-508X.2018.07.003 |
关键词: 甲醛 纳米MnOx 原位合成 催化氧化 可见光催化氧化 |
Key Words:formaldehyde nano MnOx in situ synthesis catalytic oxidation visible light photocatalytic oxidation |
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摘要:采用原位合成法制备了纳米MnOx负载纸,并对其甲醛去除性能进行了研究。纳米MnOx负载纸的甲醛去除性能与纳米MnOx颗粒的沉积率之间有一定的相关性。当KMnO4浓度为0.1 mol/L、无水乙醇用量为60 mL、反应温度和反应时间为25 ℃和2 h时,可制备出甲醛去除性能最优的纳米MnOx负载纸。扫描电子显微镜观察表明,纸浆纤维的表面沉积了纳米MnOx颗粒。X射线光电子能谱仪(XPS)分析进一步揭示了锰氧化物的生成。纳米MnOx负载纸对甲醛的去除以催化氧化为主、可见光催化氧化为辅。纳米MnOx负载纸在无光条件下仍可对甲醛进行有效去除。 |
Abstract:Nano MnOx-loaded paper was prepared via in situ synthesis process,and its performance for formaldehyde removal was studied.The performance for formaldehyde removal of nano MnOx-loaded paper had some correlation with the deposition ratio of nano MnOx particles. When the concentration of potassium permanganate (KMnO4) was 0.1mol/L, the volume of absolute ethanol was 60 mL, reaction temperature was 25 ℃ and reaction time was 2 h, the nano MnOx-loaded paper with the optimal performance for formaldehyde removal could be prepared. SEM observation indicated that nano MnOx particles were deposited on the surface of pulp fibers. The FT-IR results showed that the in situ deposition of nano MnOx particles did not change the chemical structure of cellulose. The XPS analysis further revealed the generation of MnOx . Formaldehyde was removed by the nano MnOx-loaded paper mainly via catalytic oxidation and partly via visible light photocatalytic oxidation.Formaldehyde could be effectively removed by the nano MnOx-loaded paper in dark environment. |
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