|
二维码(扫一下试试看!) |
疏水纤维素柔性凝胶材料吸附苯酚性能研究 |
Research on Adsorption of Phenol by Hydrophobic Cellulose Flexible Gel Materials |
投稿时间:2022-09-29 |
DOI:10.11980/j.issn.0254-508X.2023.06.004 |
关键词: 纤维素 苯酚废水 柔性凝胶 吸附 |
Key Words:cellulose phenol wastewater flexible gel adsorption |
基金项目:国家自然科学基金项目(21878026);2020工信部环保安全技术服务平台项目(2020-0107-3-1);江苏省科技副总项目(FZ20211438);常州市重点研发计划项目(CE20205051)。 |
|
摘要点击次数: 1844 |
全文下载次数: 1172 |
摘要:以粉末状纤维素和丙烯酰胺为单体,过硫酸钾为引发剂,N, N-亚甲基双丙烯酰胺为交联剂,制备了纤维素柔性凝胶材料(MPCs),经疏水改性处理后得到疏水纤维素柔性凝胶材料(T-MPCs),并用于吸附分离溶液中的苯酚。通过改变苯酚溶液pH值、初始浓度和吸附剂添加量,研究T-MPCs吸附苯酚的影响因素和吸附机理。结果表明,T-MPCs是一种表面多孔的柔性凝胶材料,在吸附温度25 ℃、溶液pH值7.0、吸附时间360 min、初始浓度200 mg/L的条件下,T-MPCs添加量为1000 mg/L时,其对苯酚的平衡吸附量为148.9 mg/g,吸附过程符合准二级动力学模型及Freundlich等温吸附模型,具有良好的再生能力,5次循环再生后,T-MPCs吸附性能下降15.2%。 |
Abstract:Cellulose flexible gel materials (MPCs) were prepared with cellulose powder and acrylamide as monomers, potassium persulfate as initiator and N,N-methylene diacrylamide as crosslinking agent. Then hydrophobic cellulose flexible gel materials (T-MPCs) were prepared via hydrophobic modification for MPCs and used to adsorb and separate phenol in solution. The influence factors, adsorption machanism of phenol adsorption by T-MPCs were studied by changing the pH value of solution, initial concentration of phenol solution, and adsorbent dosage. The results showed that T-MPCs were flexible gel materials with porous surface. The equilibrium adsorption capacity of phenol by T-MPCs was 148.9 mg/g, when the adsorption temperature was 25 ℃, pH value of solution 7.0, adsorption time 360 min, initial concentration of phenol 200 mg/L, and T-MPCs dosage 1000 mg/L. The adsorption process was in accordance with the pseudo-second order kinetic and Freundlich isothermal adsorption models. The adsorption capacity of phenol by T-MPCs decreased by 15.2% after 5 cycles of regeneration, indicating it is of good regeneration ability. |
查看全文 查看/发表评论 下载PDF阅读器 |