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聚磷酸铵微胶囊化改性及其制备疏水阻燃纸的研究 |
Study on Microencapsulation of Ammonium Polyphosphate and Preparation of Hydrophobic Flame Retardant Paper |
投稿时间:2022-12-19 |
DOI:10.11980/j.issn.0254-508X.2023.10.006 |
关键词: 聚磷酸铵 溶胶凝胶法 微胶囊化 阻燃 疏水 |
Key Words:ammonium polyphosphate sol-gel method microencapsulation flame retardant hydrophobicity |
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摘要:以正硅酸乙酯(TEOS)和甲基三乙氧基硅烷(MTES)为前驱体,使用溶胶凝胶法对聚磷酸铵(APP)进行微胶囊化改性,通过浆内添加法制备疏水阻燃纸。结果表明,APP为表面光滑的方形结构颗粒,具有强亲水性和负电性。在碱性条件下,TEOS和MTES共同形成致密粗糙二氧化硅壳层,将APP微胶囊化包裹。当MTES添加量为6%时,相比改性前,微胶囊化APP平均粒径由23.98 μm增至28.52 μm,水接触角从13.5°增至97.7°,由亲水性转变为疏水性,Zeta电位由-67.5 mV降至-45.8 mV,负电性减弱。与添加40%改性前APP的纸张相比,添加40%微胶囊化APP的纸张Cobb值由61.7 g/m2降至27.2 g/m2,极限氧指数(LOI)由27.1%升至31.8%,阻燃性能和疏水性能均有显著提高,达到了难燃级别。 |
Abstract:In this study, tetraethoxysilane (TEOS) and methyltriethoxysilane (MTES) were used as precursors to modify ammonium polyphosphate (APP) by sol-gel method, and then hydrophobic flame retardant paper was prepared by in-pulp addition method. The results showed that APP was a square particle with smooth surface and had strong hydrophilicity and electronegativity. Under alkaline condition, TEOS and MTES together formed a dense rough silica shell to encapsulate APP. When 6% MTES was added, the average particle size of the microencapsulated APP increased from 23.98 μm to 28.52 μm, the water contact angle increased from 13.5° to 97.7°, indicating that changed from hydrophilicity to hydrophobicity, and the Zeta potential decreased from -67.5 mV to -45.8 mV with the negative charge decreased. Compared with the paper with 40% APP, the Cobb value of the paper with 40 % microencapsulated APP decreased from 61.7 g/m2 to 27.2 g/m2, and the limiting oxygen index (LOI) increased from 27.1% to 31.8%. The flame retardancy and hydrophobic properties were significantly improved, reaching the flame-retardant level. |
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