木质素基高效染料吸附材料制备及其性能研究
Preparation of lignin-based dye adsorption materials and their performance
投稿时间:2024-03-17  修订日期:2024-04-07
DOI:
关键词:  碱木质素  吸附剂  亚甲基蓝  甲基橙  动力学  吸附等温线模型
Key Words:Alkali Lignin  Adsorbent  Methylene Blue  Methyl Orange  Kinetics  Adsorption Isotherm Model
基金项目:
作者单位邮编
温默涵 北京林业大学 100083
徐新 北京林业大学 
李丽君 北京林业大学 
黄剑波 中国制浆造纸研究院有限公司 
张学铭* 北京林业大学 100083
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摘要:工业碱木质素采用ZnCl2、KOH和尿素共同活化处理并高温炭化(700 °C),制备得到木质素基高吸附性能材料(Zn-LB)。将Zn-LB用于亚甲基蓝和甲基橙染料溶液吸附实验,探究了染料种类、吸附温度、多元混合染料体系对吸附量的影响。研究结果表明,制备的Zn-LB样品的比表面积高达2190.3 m2/g。通过Langmuir吸附等温线模型拟合了Zn-LB对亚甲基蓝和甲基橙的最大平衡吸附量分别为1345.9 mg/g和1732.4 mg/g。此外,其对亚甲基蓝的吸附量随温度的升高而升高,表明吸附亚甲基蓝是一个吸热过程;而其对甲基橙的吸附则相反,是一个放热过程。因此,所制备的木质素基吸附材料在染料废水处理领域显示出卓越的应用潜力。
Abstract:The industrial alkali lignin was subjected to co-activation treatment with ZnCl2, KOH, Urea and carbonization at a high temperature of 700°C, resulting in the production of a lignin-based adsorption material with high adsorption capacity (Zn-LB). The prepared material was then used in adsorption experiments with methylene blue and methyl orange dyes to explore the effects of dye type, adsorption temperature, and a multi-component dye system on the adsorption capacity. The study results indicated that the specific surface area of the prepared Zn-LB samples reached 2190.3 m2/g. The maximum equilibrium adsorption capacities of Zn-LB for methylene blue and methyl orange, as fitted through the Langmuir adsorption isotherm model, were 1345.9 mg/g and 1732.4 mg/g, respectively. Additionally, the adsorption capacity for methylene blue increased with temperature, indicating that the adsorption of methylene blue was an endothermic process; Conversely, the adsorption capacity for methyl orange decreased with rising temperature, suggesting an exothermic process. Therefore, the prepared lignin-based adsorbent material showed excellent application potential in the field of dye wastewater treatment.
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